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Rev. 2003 shifts occur in phase equilibria inside disordered porous medium particles 03 Zhang et al. Chem. Eng. 20 18 Empirical EoS for con ned fluid C1 C2 Co 02 VIA elmholtz energy density cm contactarea L2 moi. lr- cllon xi 34","previews":{"preview":{"ref":"track-9","$":"https://tube.tugraz.at/static/mh_default_org/engage-player/3e0d391f-c13b-479d-bd40-10842b969684/de1abc68-655a-41cc-8e57-ca91b1242351/hs1_Jul17_17_26_40.jpg"}}},{"index":15,"time":3148370,"duration":71100,"relevance":-1,"hit":false,"text":"Qiao et a1. Langmuir 20 19 bulk uid con ned uid in 510 KIJ 55 hp. Imapvglk. aj fqulhermo. PI 75 on no 02 94 ox 94 Bu Bu PM bulk densityscaling 10 Fi lip area volume Despite these considerable efforts, it is unfortunate to note that no unifying picture of various con ned uids has emerged. Is there unifying picture 40","previews":{"preview":{"ref":"track-9","$":"https://tube.tugraz.at/static/mh_default_org/engage-player/3e0d391f-c13b-479d-bd40-10842b969684/b7eab710-fb73-4564-ba9b-f01ef823f646/hs1_Jul17_17_26_40.jpg"}}},{"index":16,"time":3219470,"duration":60060,"relevance":-1,"hit":false,"text":"Outline NWOPPOMCeilza How can we include shape and size as thermodynamic variables in systematic manner 3mmm. m_ 11. Applications If kl ds ylig Thermodynamic factor activity coefficient Tm. HM Kirkwood- Buff integrals Equations of state of confined uids 1963 Transport at small scales III. Perspectives NTN 40","previews":{"preview":{"ref":"track-9","$":"https://tube.tugraz.at/static/mh_default_org/engage-player/3e0d391f-c13b-479d-bd40-10842b969684/ce4724de-20a6-451b-b2d8-22e0674da88e/hs1_Jul17_17_26_40.jpg"}}},{"index":17,"time":3279530,"duration":246170,"relevance":-1,"hit":false,"text":"How can we include shape and size as Variables 0o 9m... Hlll idea. An ensemble of small systems Thermodynamics of Small Systems TEIIELL HM Replica number N1 JVl Energy needed to include one more replica: subdivision potential CG ensemble: IU, TdS, 1dN, Eff Constant 72 IU, TdS, deV pl 6th 71V differential pressure integral pressure 40","previews":{"preview":{"ref":"track-9","$":"https://tube.tugraz.at/static/mh_default_org/engage-player/3e0d391f-c13b-479d-bd40-10842b969684/4610336d-bb9b-4dab-b6f7-777877e1ec38/hs1_Jul17_17_26_40.jpg"}}},{"index":18,"time":3525700,"duration":66500,"relevance":-1,"hit":false,"text":"How can we include shape and size as Variables Hill Gibbs Duhem equation GC ensemble. one component K1! Itf lull Nd Nanothermadynamics. General theory Relation between Ty All differential and IV integral pressure IA kBT TM Ty Thermodynamic factor","previews":{"preview":{"ref":"track-9","$":"https://tube.tugraz.at/static/mh_default_org/engage-player/3e0d391f-c13b-479d-bd40-10842b969684/5622620b-61b8-4612-abbd-36236bc82e1a/hs1_Jul17_17_26_40.jpg"}}},{"index":19,"time":3592200,"duration":60400,"relevance":-1,"hit":false,"text":"How can we include shape and size as Variables Tool: Molecular dynamics simulations WCA 65 15 2o 25 an Hafs jold et al. Mol. 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Application: The thermodynamic factor Fm Macroscopic limit particles, The energy ofa small system is re ected in its shape and size Schnell et al. M01. Phys. 2011 CP Letters 2011 11","previews":{"preview":{"ref":"track-9","$":"https://tube.tugraz.at/static/mh_default_org/engage-player/3e0d391f-c13b-479d-bd40-10842b969684/90a62187-29c0-4b80-899a-92d35f3e3a23/hs1_Jul17_17_26_40.jpg"}}},{"index":22,"time":3870170,"duration":87560,"relevance":-1,"hit":false,"text":"11. Application. The thermodynamic factor Cluster sha es different scaling SPC 80 Water 298 Dmlm ulmlmn SMM 15 UDZ 004 UD51 OLU BAOI 012 014 QIV: same scaling 41 circumradius 1H lemr 61 00 cs 07 as 09 Smam et a1. PCCP 2018 Nanomaterials 2020 area 4o","previews":{"preview":{"ref":"track-9","$":"https://tube.tugraz.at/static/mh_default_org/engage-player/3e0d391f-c13b-479d-bd40-10842b969684/c8702307-7d0e-479b-86ad-b9eddb2586a8/hs1_Jul17_17_26_40.jpg"}}},{"index":23,"time":3957730,"duration":133400,"relevance":-1,"hit":false,"text":"11. Application. The thermodynamic factor From Maxwell- Stefan to Fick formulation of diffusion in EVM 7V1n 25 7c, Vx. Thermodynamic factors needed: BW Matrix elements: with 11 71 61ny! alnxl 17 7x1 77D7 with 1171 Liu et al. Ind. Chem. Eng. Res. 2012 Schnell et al. Int. Therm. Phys. 2013 Fingerhut et al. Mol. 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Application: Transport at small scales Confined uid E05 for fcc unit cell all microstates 77V pfo yf- Qf- k1; Tln ElT. mun 2mm 2mm 13le mun 7n mm. gnu sun mu am Galteland. 0_ PhD thesis. May 2022 Hum mwlumnv kg Galteland. 0_ et al. submitted 34 40","previews":{"preview":{"ref":"track-9","$":"https://tube.tugraz.at/static/mh_default_org/engage-player/3e0d391f-c13b-479d-bd40-10842b969684/fdffb358-c133-4fd9-9011-2cdd7c80fbee/hs1_Jul17_17_26_40.jpg"}}},{"index":30,"time":4862130,"duration":100800,"relevance":-1,"hit":false,"text":"11. Application: Transport at small scales Non- equilibrium thermodynamics for small scales: thermodynamic basis for Darcy law Smallest REV 25 yum Compressxonal ux In unrnx Galteland et al. 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